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DIMETHYL(3-PHENOXY-2-OXOPROPYL)PHOSPHONATE

  • Cas number:40665-68-7
  • purity:99%
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Product Details

Chinese Manufacturer Supply DIMETHYL(3-PHENOXY-2-OXOPROPYL)PHOSPHONATE 40665-68-7 On Stock with Competitive Price

  • Molecular Formula: C11H15O5P
  • Molecular Weight: 258.211
  • Vapor Pressure: 1.16E-05mmHg at 25°C 
  • Refractive Index: 1.491 
  • Boiling Point: 369.8 °C at 760 mmHg 
  • Flash Point: 191.1 °C 
  • PSA: 71.64000 
  • Density: 1.21 g/cm3 
  • LogP: 2.12040 

DIMETHYL(3-PHENOXY-2-OXOPROPYL)PHOSPHONATE(Cas 40665-68-7) Usage

InChI:InChI=1/C11H15O5P/c1-14-17(13,15-2)9-10(12)8-16-11-6-4-3-5-7-11/h3-7H,8-9H2,1-2H3

40665-68-7 Relevant articles

He fluorine front row element intermediate preparation method (by machine translation)

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Paragraph 0034; 0035; 0036, (2018/05/16)

The invention discloses he fluorine fron...

Preparation method of beta-carboxyl phosphate

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Paragraph 0086; 0089; 0090, (2017/09/01)

The invention provides a preparation met...

Synthesis of (±) travoprost and its analogs

Mudduluru, Harikrishna,Hindupur, Rama M.,Dubey, Pramod K.,Madhavaram, Shankar,Tatini, Lakshmikumar,Subbaraju, Gottumukkala V.

experimental part, p. 234 - 241 (2012/04/18)

A new synthetic approach for the antigla...

PROSTANOIDS. XXX. SYNTHESIS OF THE ANALOGS OF 11-DEOXYPROSTA-GLANDINS E AND F

Tolstikov, G. A.,Miftakhov, M. S.,Adler, M. E.,Platonov, V. E.,Sagitdinova, Kh. F.,Khalilov, L. M.

, p. 100 - 107 (2007/10/02)

A practical approach to 11-deoxyprostagl...

40665-68-7 Process route

methyl 2-phenoxyacetate
2065-23-8

methyl 2-phenoxyacetate

dimethyl methane phosphonate
756-79-6

dimethyl methane phosphonate

dimethyl (3-phenoxy-2-oxopropyl)phosphonate
40665-68-7

dimethyl (3-phenoxy-2-oxopropyl)phosphonate

Conditions
Conditions Yield
dimethyl methane phosphonate; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere;
methyl 2-phenoxyacetate; In tetrahydrofuran; at -78 - 20 ℃; for 2.5h; Inert atmosphere;
83%
dimethyl methane phosphonate; With n-butyllithium; In tetrahydrofuran; at -78 ℃; Inert atmosphere;
methyl 2-phenoxyacetate; In tetrahydrofuran; at 25 ℃;
25%
With n-butyllithium; Yield given. Multistep reaction; 1.) THF, hexane, -78 deg C, 5 min, 2.) -78 deg C, 2 h;
With n-butyllithium; In tetrahydrofuran; hexane; water;
phenoxyacetic acid ethyl ester
2555-49-9

phenoxyacetic acid ethyl ester

dimethyl methane phosphonate
756-79-6

dimethyl methane phosphonate

dimethyl (3-phenoxy-2-oxopropyl)phosphonate
40665-68-7

dimethyl (3-phenoxy-2-oxopropyl)phosphonate

Conditions
Conditions Yield
With n-butyllithium; In tetrahydrofuran; hexane;
With n-butyllithium; In tetrahydrofuran; hexane;

40665-68-7 Upstream products

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    2065-23-8

    methyl 2-phenoxyacetate

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    34939-91-8

    dimethyl lithiomethylphosphonate

  • 756-79-6
    756-79-6

    dimethyl methane phosphonate

  • 709-84-2
    709-84-2

    bis-tetrahydropyran-2-yl ether

40665-68-7 Downstream products

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    871669-30-6

    7α-trimethylsilyloxy-6β-(3'-oxo-4'-phenoxy-1'E-butenyl)-2-oxabicyclo <3.3.0> octan-3-one

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    (Z)-7-[(1S,2R,3S,4R)-3-((E)-3-Oxo-4-phenoxy-but-1-enyl)-7-oxa-bicyclo[2.2.1]hept-2-yl]-hept-5-enoic acid methyl ester

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    methyl 9,15-dioxo-16-phenoxy-13-trans-17,18,19,20-tetranorprostenoate

DIMETHYL(3-PHENOXY-2-OXOPROPYL)PHOSPHONATE

CAS:40665-68-7

Purity:99%

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